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Thermal fractionation and identification of low-density polyethylenes

✍ Scribed by B. Wolf; S. Kenig; J. Klopstock; J. Miltz


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
397 KB
Volume
62
Category
Article
ISSN
0021-8995

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✦ Synopsis


In the present publication, a method to identify and distinguish between different types of low-density polyethylene based on thermal fractionation and FTIR analysis is described. It was shown that during thermal fractionation four to seven endothermic peaks are obtained as opposed to one or two peaks obtained during regular differential scanning calorimetric analysis. The ratio between band heights at 1368 and 1376 cm-' was found to represent the length of the side chain (branch).


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The crystallization of a series of low-density polyethylene (LDPE)-and linear low-density polyethylene (LLDPE)-rich blends was examined using differential scanning calorimetry (DSC). DSC analysis after continuous slow cooling showed a broadening of the LLDPE melt peak and subsequent increase in the