Thermal expansion of solid CH4 and CD4
β Scribed by V.G. Manzhelii; A.M. Tolkachev; V.G. Gavrilko
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 82 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0038-1098
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Fluorescence emission spectra and ion-yield spectra of CH4 and CD4 have been measured using monochromatic synchrotron radiation. We have studied the X and A ionic states in the 12-30 eV region (400-1000 ~). The visible fluorescence measurements focus upon the Rydberg series converging to vibrational
## Abstract Highβpressure Raman spectra of liquid and solid CH~4~ and CD~4~ were measured up to 18 and 13 GPa, respectively, at 300 K in a gasketed diamondβanvil cell. On the basis of visual observations under the polarizing microscope and changes in the Raman spectra, it was confirmed that there a