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Thermal expansion and interdimer exchange coupling in [Co(ethylenediamine)3]2[Cu2Cl8]Cl2 ∗ 2H2O single crystals

✍ Scribed by S.K. Hoffmann; A. Waśkowska; W. Hilczer

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
268 KB
Volume
74
Category
Article
ISSN
0038-1098

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The first selenite chloride hydrates, Co(HSeO 3 )-Cl ´3 H 2 O and Cu(HSeO 3 )Cl ´2 H 2 O, have been prepared from solution and characterised by single-crystal X-ray diffraction. The cobalt phase adopts an unusual ªone-dimensionalº structure built up from vertex-sharing pyramidal [HSeO 3 ] 2± , and o