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Thermal elimination reactions of nitrones. Part 1. Applications, limitations, and stereochemistry

โœ Scribed by Boyd, Derek R.; Neill, David C.


Book ID
118155725
Publisher
Royal Society of Chemistry
Year
1977
Weight
540 KB
Volume
11
Category
Article
ISSN
1472-7781

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Rates, Arrhenius parameters, and Hammett substituent constants are obtained for the gas-phase thermal elimination of ethyl benzoate (1) and ethyl 2 -thienyl -(2), 3thienyl -(3), 2 -furyl -(4), 3 -furyl -(5), 4 -pyridyl -(6), 3 -pyridyl -(7), and 2pyridylcarboxylate (8) esters. The log A/s ฯช1 and the