Thermal diffusivity of polymer films by pulsed photothermal radiometry

✍ Scribed by C. L. Choy; G. W. Yang; Y. W. Wong

• Publisher: John Wiley and Sons
• Year: 1997
• Tongue: English
• Weight: 227 KB
• Volume: 35
• Category: Article
• ISSN: 0887-6266
• DOI: 10.1002/(sici)1099-0488(19970730)35:10<1621::aid-polb14>3.0.co;2-c

✦ Synopsis

We have developed a pulsed photothermal radiometry technique for determining the thermal diffusivity parallel to the surface of a polymer film that involves flashing a line-shaped laser beam on the surface of the sample at right angle to its length, and monitoring the temperature change with time at a distance from the line source using an infrared detector. Combining this with our previous laser-flash radiometry method for thermal diffusivity measurement perpendicular to the film surface, we can now measure the thermal diffusivity of a polymer film along all directions. These two techniques have been used to study uniaxially and biaxially oriented poly(ethylene terephalate) and uniaxially drawn ultrahigh molecular weight polyethylene films. For uniaxially oriented poly(ethylene terephalate), the thermal diffusivity along the draw direction is substantially higher than that in the transverse direction, which in turn, is slightly higher than that in the thickness direction. For a polyethylene film with a draw ratio of 200, the axial thermal diffusivity is extremely high, being about five times that of stainless steel. The anisotropy of the thermal diffusivity of this film exceeds 90.