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Thermal decomposition reactions of n-alkylated 2-aminobiphenyls to carbazole and phenanthridine

✍ Scribed by Evelyn Cuevas Creencia; Takaaki Horaguchi


Publisher
Journal of Heterocyclic Chemistry
Year
2006
Tongue
English
Weight
335 KB
Volume
43
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

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Thermal cyclization reactions were examined by passing vapors of N‐alkylated 2‐aminobiphenyls 1a‐c and 2 over calcium oxide at 450‐600°C under nitrogen carrier gas. The reactions yielded 9‐methylcarbazole 3, carbazole 4, phenanthridine 5 and phenanthrene 6. The major product for the reactions of 1a, 1b and 2 was phenanthridine 5 while that of 1c was carbazole 4.


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