Thermal Decomposition of Trimethylgallium Ga(CH 3 ) 3 : A Shock-Tube Study and First-Principles Calculations
β Scribed by Fikri, Mustapha; Makeich, Alexander; Rollmann, Georg; Schulz, Christof; Entel, Peter
- Book ID
- 127299454
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 265 KB
- Volume
- 112
- Category
- Article
- ISSN
- 1089-5639
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## Abstract The rate coefficient for the unimolecular reaction, C~2~H~6~ β CH~3~ + CH~3~, was measured in reflected shock wave experiments using narrowβlinewidth laser absorption of methyl radicals at 216.6 nm. The experiments were conducted in the falloff regime at the conditions 1350 to 2110 K, 0
## Abstract The rate coefficient for NH~2~ + CH~4~ β NH~3~ + CH~3~ (R1) has been measured in a shock tube in the temperature range 1591β2084 K using FM spectroscopy to monitor NH~2~ radicals. The measurements are combined with a calculation of the potential energy surface and canonical transition s