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Thermal decomposition of potassium persulfate in aqueous solution at 50°C in an inert atmosphere of nitrogen in the presence of acrylonitrile monomer

✍ Scribed by Swati Sarkar; Mukti Sadhan Adhikari; Monoranjan Banerjee; Ranajit Singha Konar


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
800 KB
Volume
35
Category
Article
ISSN
0021-8995

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The rate of the thermal decomposition of potassium persulfate has been studied in an unbuffered aqueous solution a t 50°C in nitrogen atmosphere in the presence of vinyl acetate (VA) monomer (M). I t has been found that the initial rate of persulfate decomposition may be written as -d(&o,2-)/dt (S20

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The initial rate of persulphate ( I ) decomposition at 50°C in the presence of nitrogen and methacrylonitrile (MAN) in an unbuffered aqueous solution (pH 4-7) may be written as: -d(SzOg-)/dt cc (MAN)1.29'0.05 x (I) 1.20-tO.04 in the concentration ranges of persulphate ( I ) (0.25-2.50) X lo-' ( m/d