## Abstract Rapidβscan FTIR/temperature profiling studies of the fast thermal decomposition of alkanediammonium dinitrate salts [H~3~N(CH~2~)~n~NH~3~](NO~3~)~2~, n = 1β4 and 6, are described. All of the salts liberate HNO~3~ and NH~3~ early in the first stage. When n = 1β3, small molecule products
Thermal Decomposition of Energetic Materials. 43. Fast thermolysis of cubylammonium nitrate and cubane-1,4-diammonium dinitrate
β Scribed by T. P. Russell; T. B. Brill
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 359 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0721-3115
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High-heating-rate (< 100\*C/s) thermolysis studies at various pressures (1-1000 psi) are described for NH4NO3(AN), [NH3CH2CH2NH3](NO3)2(EDDN), [NH2NH3](NO3)(HN), 50/50 AN/EDDN, and 67/33 HAN/HN (HAN = hydroxylammonium nitrate) by using the rapid-scan FTIR/thermal profiling technique. For all of the
## Abstract Fast thermolysis/FTIR spectroscopy of [H~3~NCH~2~CH~2~NH~3~]β(NO~3~)~2~ (EDD), [H~2~N(CH~2~CH~2~)~2~NH~2~](NO~3~)~2~ (PIPDN), and [HN(CH~2~CH~2~)~3~NH](NO~3~)~2~(DABCOD) and new oxonium nitrate (H~3~O^+^NO^β3^) double salts of PIPDN and DABCOD is described. EDD initially yields HNO~3~ a
## Abstract The fast thermolysis of Nβmethyl substituted ethanediamβmonium dinitrate salts is described by temperature profiling/FTIR spectroscopy. The salts described are [CH~3~NH~2~CH~2~CH~2~NH~3~](NO~3~)~2~ (MEDD), [CH~3~NH~2~CH~2~CH~2~NH~2~CH~3~](NO~3~)~2~ (SDMEDD), [(CH~3~)~2~NHCH~2~CH~2~NH~3~
## Abstract Temperature profiling/FTIR is described for the fast thermolysis of four CβNO~2~βcontaining nitramines whose oxygen content exceeds the balance to CO~2~. The compounds are [(NO~2~)~3~CCH~2~N(NO~2~)CH~2~β]~2~ (ONDO), [(NO~2~)~3~CCH~2~]~2~N(NO~2~) (BTNEN), [Cl(NO~2~)~2~CCH~2~]~2~N(NO~2~)
## Abstract Fast thermolysis studies of ammonium nitrate (AN) and its mixtures with magnesium and activated charcoal have been carried out by the Fourier transform infrared spectroscopy/temperature profiling technique. When subjected to rapid heating (ca. 80Β°C/s), AN Sublimes/decomposes around 300Β°