Thermal decomposition of energetic materials. 25. Shifting of the dominant decomposition site by backbone substitution of alkylammonium nitrate salts

Thermal Decomposition of Energetic Mater

Thermal Decomposition of Energetic Materials 41. Fast thermolysis of cyclic and acyclic ethanediammonium dinitrate salts and their oxonium nitrate double salts, and the crystal structure of piperazinium dinitrate

✍ T. P. Russell; T. B. Brill; A. L. Rheingold; B. S. Haggerty 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 576 KB

## Abstract Fast thermolysis/FTIR spectroscopy of [H~3~NCH~2~CH~2~NH~3~]‐(NO~3~)~2~ (EDD), [H~2~N(CH~2~CH~2~)~2~NH~2~](NO~3~)~2~ (PIPDN), and [HN(CH~2~CH~2~)~3~NH](NO~3~)~2~(DABCOD) and new oxonium nitrate (H~3~O^+^NO^−3^) double salts of PIPDN and DABCOD is described. EDD initially yields HNO~3~ a