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Thermal decomposition of energetic materials 13. High-rate thermolysis of benzofuroxans and 3,4-dimethylfuroxan

โœ Scribed by Y. Oyumi; T.B. Brill

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
356 KB
Volume
65
Category
Article
ISSN
0010-2180

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โœฆ Synopsis

The rapid thermal decomposition of five substituted benzofuroxans and a 3,~-dimethylfuroxan was examined by rapid-scan FTIR spectroscopy as a function of heating rate and pressure. The product distribution and parent molecular structure proved difficult to correlate in the benzofuroxan series, but it is distinctly different from the alkylfuroxan. Rapid heating cleaves 3,4-dimethylfuroxan into two equivalents of acetonitrile N-oxide, whereas only small molecule fragments are produced by benzofuroxans.

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