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Thermal Decomposition of di- tert -Butyl Peroxide in Binary Mixtures near the Critical Point

✍ Scribed by Yip, C. K.; Pritchard, H. O.

Book ID
120000997
Publisher
NRC Research Press
Year
1971
Tongue
French
Weight
247 KB
Volume
49
Category
Article
ISSN
0008-4042

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The effects of pressure and of the composition of the CO2/ethanol mixed solvent in the critical region on the kinetics of the decomposition of 2,2'-azobis(isobutyronitrile) (AIBN) were studied at 333.15 K. The rate constants (kd) in the mixed solvent far from the critical point and in liquid n-hexan