✦ LIBER ✦

Thermal decomposition of CH3I using I-atom absorption

✍ Scribed by S. S. Kumaran; M.-C. Su; J. V. Michael

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 156 KB
Volume: 29
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1997)29:7<535::aid-kin8>3.0.co;2-v

No coin nor oath required. For personal study only.

✦ Synopsis

The recently developed I-atom atomic resonance absorption spectrometric (ARAS) technique has been used to study the thermal decomposition kinetics of CH 3 I over the temperature range, 1052 -1820 K. Measured rate constants for CH 3 I between 1052 and 1616 K are best expressed by k . Two unimolecular theoretical approaches were used to rationalize the data. The more extensive method, RRKM analysis, indicates that the dissociation rates are effectively second-order, i.e., the magnitude is 61 -82% of the low-pressure-limit rate constants over 1052 -1616 K and 102 -828 torr. With the known , the optimized RRKM fit to the ARAS data requires .

📜 SIMILAR VOLUMES

Thermal decomposition of CF3Br using Br-

Thermal decomposition of CF3Br using Br-atom absorption

✍ J. Hranisavljevic; J. J. Carroll; M.-C. Su; J. V. Michael 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 185 KB 👁 1 views

Br-atom atomic resonance absorption spectrometry (ARAS) has been developed and applied to measure thermal decomposition rate constants for CF Br (ϩ Kr) : CF ϩ 3 3 over the temperature range, 1222-1624 K. The Br-atom curve-of-growth Br (ϩ Kr) (145 Ͻ was determined using this reaction. For molecules c

Structure of Triphenylarsane Diiodide, [

Structure of Triphenylarsane Diiodide, [Ph3As · I2], a Compound Formed in the Thermal Decomposition of [Mn(OAsPh3 )3I2 (SO2)2]

✍ Prof. Dr. Charles A. McAuliffe; Dr. Brian Beagley; Dr. George A. Gott; Anthony G 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 230 KB

Thermal decomposition of cyclotriphospha

Thermal decomposition of cyclotriphosphazenes. I. Alkyl-aminoaryl ethers

✍ S. V. Levchik; G. Camino; M. P. Luda; L. Costa; A. Lindsay; D. Stevenson 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 299 KB 👁 2 views

1,3,5 -Triisopropoxy-1,3,5 -tris(4 -aminophenoxy) -cyclotriphosphazene-[CTP (I)], 1,3,5 -trineopentoxy-1,3,5 -tris(4 -aminophenoxy) -cyclotriphosphazene [CTP (II)], and 1,1,3,5-tetraneopentoxy-3,5-bis(4-aminophenoxy) -cyclotriphosphazene [CTP (III)] were prepared from hexachlorotricylophosphazene. T

Thermal decomposition of additive polyme

Thermal decomposition of additive polymerization initiators. I. Azobisisobutyronitrile

✍ Hideki Sasaki; Masako Nagayama 📂 Article 📅 1967 🏛 John Wiley and Sons 🌐 English ⚖ 476 KB

Kinetics and Mechanism of Thermal Decomp

Kinetics and Mechanism of Thermal Decomposition of Dinitramide

✍ Anatolii I. Kazakov; Yurii I. Rubtsov; Georgii B. Manelis 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 108 KB 👁 2 views

Shock tube study of monomethylamine ther

Shock tube study of monomethylamine thermal decomposition and NH2 high temperature absorption coefficient

✍ M. Votsmeier; S. Song; D. F. Davidson; R. K. Hanson 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 1 views

CH 3 NH 2 thermal decomposition is shown to provide a suitable NH 2 radical source for spectroscopic and kinetic shock tube studies. Using this precursor, the absorption coefficient of the NH 2 radical at a detection wavelength of 16739.90 cm Ϫ1 has been determined. In the temperature range 1600-200