Thermal decomposition of (CH3)2SnX2 (XF, SO3F, or SO3CF3)
✍ Scribed by S.P. Mallela; R.A. Geanangel; W.W. Wendlandt
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 450 KB
- Volume
- 156
- Category
- Article
- ISSN
- 0040-6031
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The title compounds are the first examples of solvent‐free oxide methanesulfonates of Mo, U, Re, and V.
3 ) 3 . The reaction proceeds with high regioselectivity. Thus, methanesulfonylation of 1,2,4-trifluorobenzene (V) exclusively affords the 1-mesyl-2,4,5-trifluorobenzene (VI). In dihalobenzenes [cf. compounds (VII) and (Ia)], the para-position is predominantly substituted [cf. compound (VIII)]. Othe
La(CH 3 SO 3 ) 3 ´2 H 2 O was prepared by the reaction of La 2 O 3 with CH 3 SO 3 H. According to the X-ray single crystal determination, the compound crystallizes with triclinic symmetry (P 1, Z = 2, a = 524.99( 8), b = 1015.3(2), c = 1298.0(2) pm, a = 98.62(2)°, b = 91.12(2)°, c = 104.61(2)°, R al