Haloacetyl peroxynitrates are intermediates in the atmospheric degradation of a number of haloethanes. In this work, thermal decomposition rate constants of CF3C(0)02N02, CClFzC(0)02N02, CC12FC(0)02N02, and CC13C(0)02N02 have been determined in a temperature controlled 420 1 reaction chamber. Peroxy
Thermal decomposition of Ba(NO2)2 · H2O
✍ Scribed by P.K. Gallagher
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 361 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-6031
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## Abstract The thermal decomposition of trifluoromethoxycarbonyl peroxy nitrate, CF~3~OC(O)O~2~NO~2~, has been studied between 278 and 306 K at 270 mbar total pressure using He as a diluent gas. The pressure dependence of the reaction was also studied at 292 K between 1.2 and 270 mbar total pressu
Ihe reactions of CC1302 with NO and NO2 have been studied by steady-state photolqsis of Clz-HCCl,-Oz-&-NO --NOz mixtures at =I atm: CCl30, + NO -Ccl,0 + NO, (3), CCt,O, + NO2 (t hl) \* CCl,02NOt (+ hi) (4. A); k&k3 = 0.68, independent of temperature-The thermal decomposition of CC1302N02 via the bac