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Thermal decomposition of azobis(isobutyronitrile) in the solid state. Cage effect. Recombination and disproportionation of cyanoisopropyl radicals

✍ Scribed by V. V. Dubikhin, E. I. Knerel’man, G. B. Manelis, G. M. Nazin, V. G. Prokudin, G. A. Stashina, N. V. Chukanov, A. V. Shastin

Book ID
118277201
Publisher
SP MAIK Nauka/Interperiodica
Year
2012
Tongue
English
Weight
188 KB
Volume
446
Category
Article
ISSN
0012-5016

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Initial Radical Separation after Photoly
Initial Radical Separation after Photolysis of 2,2′-Azobis(isobutyronitrile) (AIBN) in Solution: Modeling the Primary Cage Effect for Polar Radicals
✍ Anton N. Savitsky; Henning Paul; Anatoly I. Shushin 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 148 KB

## Abstract There is a contradiction as to the initial spatial separation __r__~i~ of the two transient 2‐cyanoprop‐2‐yl radicals (Me~2~$\rm{{{\dot C}}}$CN) formed by flash photolysis of 2,2′‐azobis(isobutyronitrile) (AIBN) in solvents of various viscosities. The cage effect, expressed in terms of