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Thermal decomposition of 3-chloro-3-trichloromethyldiazirine in solution

โœ Scribed by Michael T. H. Liu; K. Toriyama

Book ID
102443974
Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
225 KB
Volume
4
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

The thermal decomposition of 3-chloro-3-trichloromethyldizairine in carbon tetrachloride and iso-octane has been investigated over the temperature range 75-1 15OC. The products, tetrachloroethylene and nitrogen, are formed quantitatively by a first-order reaction which is probably unimolecular: CCls N C1 c1 The results yielded the following Arrhenius equations: k (CCI,) = 1013.8*o.2 exp (-29,200 & 200/RT) sec-' k (iso-octane) = 1 0 1 3 . 8 * a . 2 exp (-29,000 f 150/RT) sec-'

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