Electron paramagnetic resonance spectroscopy has been used to probe the decomposition pathway of neat molten 2,4,6-trinitrotoiuene (TNT). The analogs of TNT labelled in the 2-, 2,6-, 4-and 2,4,6positions with =N, and labelled in the it-, 3,s-and a,3,5-position with \*H have been studied, and their s
Thermal decomposition of 2,4,6-trinitrotoluene during the induction period
✍ Scribed by A. Ksia̧żczak; T. Ksia̧żczak
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 367 KB
- Volume
- 275
- Category
- Article
- ISSN
- 0040-6031
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The products of sublimation and thermal decomposition of 1,3,5-triamino-2,4,6-trinitmbenzene have been determined mass spectrometrically in the temperature range 200-300°C employing both the effusion and Langmuir evaporation methods. Electron impact ionization energies 1-2 eV above appearance potent