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Thermal Decomposition Mechanisms of tert -Alkyl Peroxypivalates Studied by the Nitroxide Radical Trapping Technique

✍ Scribed by Nakamura, Tomoyuki; Busfield, W. Ken; Jenkins, Ian D.; Rizzardo, Ezio; Thang, San H.; Suyama, Shuji


Book ID
126465846
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
214 KB
Volume
65
Category
Article
ISSN
0022-3263

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The radical trapping technique employing the stable nitroxide 1 as a scavenger has been used to study the reaction of t-butoxyl radicals with diethyl fumarate and with diethyl maleate. The major pathway with both monomers is hydrogen abstraction from the ester alkyl groups by t-butoxyl radicals. The