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Thermal cracking of JP-10: Kinetics and product distribution

✍ Scribed by P. Nageswara Rao; Deepak Kunzru

Publisher: Elsevier Science
Year: 2006
Tongue: English
Weight: 317 KB
Volume: 76
Category: Article
ISSN: 0165-2370
DOI: 10.1016/j.jaap.2005.10.003

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✦ Synopsis

The product distribution and kinetics of thermal cracking of JP-10 (exo-tetrahydrodicyclopentadiene) were investigated in an annular tubular reactor at atmospheric pressure, in the temperature range of 903-968 K. No inerts were added with the feed. The major products were methane, ethylene, propylene, cyclopentene, cyclopentadiene, benzene and toluene. The pre-exponential factor, activation energy and overall reaction order for thermal cracking of JP-10 were determined by non-linear regression analysis to be 2.4 Â 10 13 (m 3 /mol) 0.1 s À1 , 256.2 kJ/mol and 1.1, respectively.

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