✦ LIBER ✦

Thermal conductivity of polycrystalline graphite

✍ Scribed by R. Taylor; K.E. Gilchrist; L.J. Poston

Publisher: Elsevier Science
Year: 1968
Tongue: English
Weight: 630 KB
Volume: 6
Category: Article
ISSN: 0008-6223
DOI: 10.1016/0008-6223(68)90093-6

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✦ Synopsis

Measurements of thermal conductivity from 100 to 900°K and electrical resistivity at 80°K have been made on two mutually perpendicular directions of two types of anisotropic polycrystalline graphites and of two isotropic graphites of different densities. The thermal conductivity curves can be fitted using expressions calculated for thermal resistance due to boundary and isotope scattering and a relationship for Umklapp scattering derived from pyrolytic graphite. By invoking a factor to account for the reduction in conductivity due to porosity and irregular arrangement of crystallites in polycrystalline graphite, crystallite sizes values are obtained from thermal conductivity analysis. Crystallite sizes obtained from electrical resistivity measurements using the simple two band model are about Z/3 those derived from thermal conductivity and various reasons are suggested to explain the difference.

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