Thermal characterization of the polymerization of methyl methacrylate
โ Scribed by J.A. Feliu; C. Sottile; C. Bassani; J. Ligthart; G. Maschio
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 450 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0009-2509
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โฆ Synopsis
Two different calorimetric techniques have been used to determine thermokinetic parameters and to asses the thermal stability of bulk methyl methacrylate (MMA) polymerization. The results obtained with both methods are in agreement with those reported in the literature. New correlations based on experimental results have been proposed to describe the influence of diffusion phenomena on the dynamics of the process. A mathematical model based on the experimental results has been developed in order to execute an analysis of the dynamics of the process.
๐ SIMILAR VOLUMES
Bulk polymerizations of methyl methacrylate (MMA) with n-hexyl acrylate (HA) or 2-ethylhexyl acrylate (EHA) were carried out using benzoyl peroxide as initiator. Polymer samples were prepared for mole fractions of HA or EHA from 0 to 1 in the initial feed. Molecular characterization of the copolymer