Thermal stabilities of copolymers of acrylonitrile with 4-14 mol% of 3-chloro-2-hydroxypropyl acrylate or methacrylate, 2-chloroethyl acrylate or methacrylate and 2-bromoethyl acrylate or methacrylate were studied by TGA in air. A two-step degradation between 30(1 and 350 ° and 600 and 650 ° is obse
Thermal behaviour of the copolymers of acrylonitrile with methyl acrylate and itaconic acid or its derivatives
✍ Scribed by Shlyakhtin, Andrei V.; Lemenovskii, Dmitrii A.; Nifant’ev, Ilya E.
- Book ID
- 121829879
- Publisher
- Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 351 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0959-9436
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## Abstract This article reports data on the dynamic mechanical and thermal behaviour of butyl acrylate‐acrylonitrile copolymers and their variation with copolymer composition. The copolymers were prepared by emulsion polymerisation techniques, using potassium peroxodisulfate initiator at 80 ± 2 °C
Ternary copolymerization of tri-n-butyltin acrylate (TBTA) or methylacrylate (TBTMA) with itaconic acid (IA) or dimethyl itaconate (DMI) and acrylonitrile ( A N ) were carried out in solution at 70°C in the presence of a free radical initiator. Experimental terpolymerization data agreed well with ca