An amorphous phase has been synthesized by mechanical alloying in a planetary mill over a nickel content range of 10-70 at.% in the Ti-Ni system and a copper content range of 10-50 at.% in the Ti-Cu system. In the case of ternary Ti-Ni-Cu alloys the glass-forming composition range has been found to
Thermal behaviour of CuTi and CuTiH amorphous powders prepared by ball milling
✍ Scribed by M. Baricco; L. Battezzati; I. Soletta; L. Schiffini; N. Cowlam
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 275 KB
- Volume
- 134
- Category
- Article
- ISSN
- 0921-5093
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✦ Synopsis
Solid state amorphization reactions in Cu-Ti have been studied by means of DSC and structural techniques. The influence of hydrogen from the parent titanium powder on the amorphization and crystallization processes has been investigated. For Cu-Ti a diffusion-controlled process can be inferred for solid state amorphization from the parabolic trend of the heat of crystallization, as a function of the milling time. The presence of hydrogen in the alloys is found to modify the crystallization behaviour of the amorphous phase. A DSC method for the determination of the amount of hydrogen present in the alloys is given.
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