✦ LIBER ✦
Thermal and Photochemical Reactions of Azidoruthenium(III) Complexes of Macrocyclic Tertiary Amines and the Structure of the (Phosphoraniminato)ruthenium(III) Complex trans-[Ru(14-TMC)(N3)(NPPh3)]+
✍ Scribed by Chi-Ming Ho; Hiu-Chi Leung; Shuixing Wu; Kam-Hung Low; Zhenyang Lin; Chi-Ming Che
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 640 KB
- Volume
- 2012
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
The bis(azido)ruthenium(III) complexes, trans-[Ru(L)(N 3 ) 2 ] + [L = 14-TMC (1) and 16-TMC (4)] have been prepared. These complexes undergo facile thermal or photo-decomposition in RCN (R = Me, Bu, Ph, 4-MePh, 2-MeOPh) solutions to produce the corresponding azidoruthenium(II) complexes trans-[Ru(L)(N 3 )(RCN)] + [L = 14-TMC, R = Me (2a), Bu (2b), Ph (2c), 4-MePh (2d), 2-MeOPh (2e); L = 16-TMC, R = Me (5a), = Ph (5b)] and cis-[Ru(Tet-Me 6 )(N 3 )(MeCN)] + (6). Complex 1 reacted with PPh 3 , by a nitrogen atom transfer reaction, to