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Thermal and photochemical decomposition of 7,8-diazatetracyclo[3.3.0.02,4.03.6]oct-7-ene. 1,2-Diazacycloocta-2,4,5,8-tetraene

โœ Scribed by Trost, Barry M.; Cory, Robert M.


Book ID
120865705
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
385 KB
Volume
93
Category
Article
ISSN
0002-7863

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Tetracyclo[4.1.0.02,4.03,5]heptanes from
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which is converted by cleavage of CO, into the products in a thermodynamic E/Z ratio (E/Z= 9/1). ## Tetracyclo [4.1.0.02~4.03~5)heptanes from 7,8-Diazatetracyclo14.3.0.0z~4.03~s~non-7-enes I\*\*]

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In order to investigate and probe the possible mechanism of rearrangement of trans-hexaphenyldifluorotricyclooctadiene, (a dimer of fluorotriphenylcyclobutadiene), to pentaphenyldihydrodifluoropentalene via C-F bond migration (Choudhury et al.,2007), a high temperature study of the title compound wa