Thermal analysis and spectroscopic studies of some complexes of l,7-diacetoxy-2,4,6-trinitro- 2,4,6-triazaheptane
โ Scribed by R.E. Cobbledick; L.E.D. Davies; R.W.H. Small; D. Stubley
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 535 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-6031
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## Abstract magnified image A series of 4โthiazolidinones having triazinethione moieties have been synthesized by the systematic chemical modification of Sโbenzylmercaptoโ1โarylโ4โ(4โmethoxyphenyl)โ1,6โdihydroโ1,3,5โtriazineโ6โthione.
Results of IR and 1 H, 13 C, and 31 P NMR studies of the anancomeric title compounds (2-5) and compound 1 (Scheme 1) are analyzed to search for the existence of high-energy boat or twist-boat conformations in the equatorial epimers. While the difference in frequencies (Dm) PโซืกโฌO between the axial an