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Thermal addition of xathenethione to allenes: “A Concerted Two Step” (π2s+π2s+π2s)-cycloaddition

✍ Scribed by J. Kamphuis; R.G. Visser; H.J.T. Bos

Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
128 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis

2+2)and (4+2)-cycloadducts are formed by thermal reaction of xanthenethione with allenes. Activation parameters for this "concerted two step" (a2s+s2s+n2S) reaction are presented.

Photochemical addition of thiones to allenes have well been studied'. However, thermal addi-

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