The transfer behavior of both acidic and basic dyes at the interface between water and some organic solvents has been studied in detail by electrochemical methods, and a transfer mechanism is proposed for both acidic and basic dyes. The equations of interfacial half-wave potentials for both dyes are
Theory of the kinetics of ion transfer across liquid/liquid interfaces
β Scribed by H.H.J. Girault; D.J. Schiffrin
- Publisher
- Elsevier Science
- Year
- 1985
- Weight
- 913 KB
- Volume
- 195
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
The impedance or admittance measurement of ion transfer across immiscible electrolyte interfaces involves measuring quantities which are non-linear functions of frequency and model parameters. To extract the kinetic information from the data, non-linear regression techniques must be used. A Quasi-Ne
the ion-transfer kinetic model at the immiscible liquid/liquid interface presented here, the transfer of an ion is controlled by an activation energy and velocity of the ion in the viscous interface. The model was enlightened by the insufficient agreement of the potential dependence of the experimen