The slow-motion theory of nuclear spin relaxation in paramagnetic low-symmetry complexes is generalized to comprise arbitrary values of S. We describe the effects of rhombic symmetry in the static zero-field splitting (ZFS) and allow the principal axis system of the static ZFS tensor to deviate from
Theory of spin relaxation in the limit of slow motion. Nuclear and electron spin relaxation in paramagnetic transition-metal complexes
β Scribed by Pegg, DT; Doddrell, DM
- Book ID
- 120659823
- Publisher
- Commonwealth Scientific and Industrial Research Organisation Publishing
- Year
- 1976
- Tongue
- English
- Weight
- 638 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0004-9425
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Proton spin-lattice (T1) and spin-spin (T2) relaxation times have been measured for CH3 protons in a series of paramagnetic transition-meta! acetylacetonatc complexes and the results interpreted in terms of current relaxation theory. r&the correlation time for molecular reorientation, was estimated
r3C spin-lattice relaxation times have been measured for some of the ligand positions of some metal acetylacetonate complexes. The results suggest that the relaxation process is dominated by dipolar interactions with unpaired eiectron spin residing on the ligand. A simple analysis of ligand-centred