Theory of spectroelectrochemistry under galvanostatic conditions—II. Irreversible and quasi-reversible simple charge transfer reactions
✍ Scribed by Zbigniew Uziel
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 388 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
This paper deals with a ;zw mathematical formulation ofkyhethods for spectroelectrochemical examination of irreversible 0 + M-A R and quasi-reversible 0 + M--_ R simplecharge transfer reactions 4.. on planar electrodes under conditions of semi-infinite linear diffusion making use of electrolysis under galvanostatic conditions. It is a continuation of previous theoretical considerations published in Part I of this series. The principal equations relating to electrode potential and transition absorbances of the spectrally monitored species 0 or R are derived. A possibility of determining the parameters of electrode process from measurements by transmission or reflection spectroscopy methods is presented.