✦ LIBER ✦

Theory of simple fluids near a structured surface

✍ Scribed by M.-E. Boudh-Hir

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 665 KB
Volume: 154
Category: Article
ISSN: 0378-4371
DOI: 10.1016/0378-4371(88)90184-7

No coin nor oath required. For personal study only.

✦ Synopsis

Convenient theoretical methods for calculating structure and thermodynamic properties of fluids near an irregular hard wall are developed. Using the diagrammatic expansion, we prove that: Firstly, a fluid system in contact with an irregular surface can be treated as two coupling fluids. The first one is defined by the studied fluid interacting with a planar hard wall. It is called the reference system. The second, which is referred to as the fictitious system, is confined to the surface cavities. Secondly, these developments can be used to find a self-consistent approximation.

📜 SIMILAR VOLUMES

A simple theory of weakly inhomogeneous

A simple theory of weakly inhomogeneous fluids

✍ A.G. Schlijper; B. Smit 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 515 KB

A new theory of simple classical fluids

✍ Yaakov Rosenfeld; N.W. Ashcroft 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 542 KB

Fluctuation theory of hydrogen bonding i

Fluctuation theory of hydrogen bonding in near-critical fluids

✍ Boris A. Veytsman; Ram B. Gupta 📂 Article 📅 1996 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 631 KB

## Abstract Recent experiments indicate that the number of hydrogen bonds in solutions increases in the critical region of the solvent. This effect can be explained by the density fluctuations near the critical point. A theory of this unusual effect is developed. The theoretical predictions are com

A new, accurate, statistical mechanical

A new, accurate, statistical mechanical theory for simple fluids

✍ Forrest J. Rogers; David A. Young 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 132 KB

Near-critical fluid interfaces: A compar

Near-critical fluid interfaces: A comparison of theory and experiment

✍ James W. Schmidt 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 987 KB

Transport of simple fluids in nanopores:

Transport of simple fluids in nanopores: Theory and simulation

✍ Suresh K. Bhatia; David Nicholson 📂 Article 📅 2005 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 173 KB 👁 2 views

## Abstract A theory is discussed of single‐component transport in nanopores, recently developed by Bhatia and coworkers. The theory considers the oscillatory motion of molecules between diffuse wall collisions, arising from the fluid–wall interaction, along with superimposed viscous flow due to fl