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Theory of relativistic effects on atoms: Configuration-space Hamiltonian

✍ Scribed by Mittleman, Marvin

Book ID
115537111
Publisher
The American Physical Society
Year
1981
Tongue
English
Weight
497 KB
Volume
24
Category
Article
ISSN
1050-2947

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Dependence of relativistic effects on el
Dependence of relativistic effects on electronic configuration in the neutral atoms of d- and f-block elements
✍ J. Autschbach; S. Siekierski; M. Seth; P. Schwerdtfeger; W. H. E. Schwarz πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 229 KB πŸ‘ 1 views

Although most neutral d- and f-block atoms have nd(g-2)(n + 1)s(2) and (n - 1)f(g-2)(n + 1)s(2) ground configurations, respectively, where g is the group number (i.e., number of valence electrons), one-third of these 63 atoms prefer a higher d-population, namely via (n + 1)s-->nd "outer" to "inner"