## Abstrac -An electrode reaction coupled with dismutation of the reduction product is treated mathematically for the case of a porous oxygen electrode in an alkaline medium. The electrode is regarded as a superposition of three continuous phases and the changes of the electrolyte concentration ar
Theory of porous electrodes—XVIII. The iron electrode
✍ Scribed by K. Micka; I. Roušar
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 634 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
✦ Synopsis
Abslract
-A model of the negative plate of the Ni-Fe accumulator is proposed, similar to that of the negative plate of the Ni-Cd accumulator. Besides volume changes of the solid phase and other obvious effects, the dependence of the tortuosity factor of the pores on porosity was also taken into account. The best agreement with the theory is obtained with electrodes prepared from pure sintered iron powder, eventual deviations being attributed to partial passivation. The influence of various factors is discussed in detail.
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