Theory of nuclear magnetic spin-rotational relaxation for asymmetric molecules
โ Scribed by James McConnell
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 768 KB
- Volume
- 152
- Category
- Article
- ISSN
- 0378-4371
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๐ SIMILAR VOLUMES
The variation-perturbation method, employing an explicitly correlated basis set in the form of Gaussian functions with exponential correlation factors, has been used to calculate the paramagnelic component of the nuclear magnetic shielding and the electronic contribution to the spin-rotation constan
A generalization of the modified Solomon-Bloembergen-Morgan (MSBM) equations has been derived in order to describe paramagnetic relaxation enhancement (PRE) of paramagnetic complexes characterized by both a transient (โฌ t ZFS ) and a static (โฌ s ZFS ) zero-field splitting (ZFS) interaction. The new