## Abstract Serviceable NMR spectra can, with a few exceptions^[1,6]^, be recorded for paramagnetic complexes in solution. These spectra provide information about the structure of the complexes and the distribution of the unpaired electrons, and hence also about reactive centers in the molecule. Th
Theory of NMR shifts and endor spectroscopy in paramagnetic complexes
β Scribed by H. Eicher
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 736 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The methylated metallocenes (MeCp)~2~M with M = V, Cr, Mn, Co, Ni (1β5) were investigated by ^1^H and ^2^H NMR spectroscopy at natural abundance. The ^2^H NMR signals are narrower by a factor of up to 30 compared with the corresponding ^1^H NMR signals, thus establishing an inexpensive
## Abstract A fitting procedure is descdribede to establish the conformation and molecular dynamics of flexible molecules coβordinated to lanthanide cations from NMR paramagnetic shift data of ^1^H and ^13^C resonances. The results from Lβproline and Lβvaline in aqueous solution at low pH values ar