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Theory of Fast Capillary Gas Chromatography - Part 3: Column Performancevs. Gas Flow Rate

โœ Scribed by Blumberg, Leonid M.


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
133 KB
Volume
22
Category
Article
ISSN
0935-6304

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Theory of Fast Capillary Gas Chromatogra
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The negative effect of the liquid stationary phase film thickness on the column efficiency is strongest for peaks with retention factors, k, in the vicinity of k = 0.3 -0.4 and rapidly diminishes with the departure of k from that region. Additionally, at the high pressure drop required for fast anal

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When the column pressure drop is high, the average velocity of a carrier gas is proportional to the square root of the outlet velocity and the flow rate. Characteristic velocity, flow rate and pressure -the boundary conditions between low and high pressure drop regionsare introduced. Previously deri