Theory of activated reaction processes: Non-linear coupling between reactive and non-reactive modes

✍ Scribed by Mario Compiani; Teresa Fonseca; Paolo Grigolini; Roberto Serra

• Publisher: Elsevier Science
• Year: 1985
• Tongue: English
• Weight: 367 KB
• Volume: 114
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(85)85129-0

✦ Synopsis

Deviations from the Kramers preditions resulting from the couplmg between a reactive and a non-reactwe mode are studied in both the low-and hi&-diction Iimits. It is alsO argued how this simple picture may provide a breakdown of the upper Iimit imposed on the relaxation rate by transdion state theory.