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Theory and simulations of macroion complexation

โœ Scribed by Renko de Vries; Martien Cohen Stuart


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
427 KB
Volume
11
Category
Article
ISSN
1359-0294

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โœฆ Synopsis


A brief overview is given over recent theoretical and simulation work on complexes of oppositely charged macroions. The emphasis is on linear/ cylindrical macroions (flexible, semiflexible polyelectrolytes) and spherical/globular macroions (colloids, micelles, globular proteins). We discuss soluble complexes, dense complex phases, and micelles with cores consisting of dense complex phases, stabilized by neutral hydrophilic chains.


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Various models of the complex formation between polyelectrolyte chains and oppositely charged macroions are reviewed. In recent years, a great deal of knowledge of the multitude of possible polyelectrolyte conformations at the macroion surface has been accumulated, which consequently has led to incr