Theory and simulation of proton-coupled electron transfer, hydrogen-atom transfer, and proton translocation in proteins
β Scribed by R.I. Cukier
- Book ID
- 116270077
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 256 KB
- Volume
- 1655
- Category
- Article
- ISSN
- 0005-2728
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π SIMILAR VOLUMES
A comparison of hydride, hydrogen atom, and proton-coupled electron transfer reactions is presented. Herein, hydride and hydrogen atom transfer refer to reactions in which the electrons and protons transfer between the same donor and acceptor, while proton-coupled electron transfer (PCET) refers to
It is shown that electron transfer in proteins is not very dependent on protein structure but is considerably aided by donor/acceptor group orientations. The value of structure within proteins is very largely due to overall atomic packing, and since proteins generally are equally packed, the separat