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Theory and application of chemically modified carbon paste electrode to copper speciation determination

✍ Scribed by J. Labuda; H. Korgová; M. Vaníčková


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
568 KB
Volume
305
Category
Article
ISSN
0003-2670

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✦ Synopsis


The determination and speciation of copper at a carbon paste electrode modified with Dowex 5OW-8X cation-exchange resin was investigated in model and real samples. With this procedure free metal ions and labile complexes can be measured which dissociate during the time scale of the chemical accumulation of copper at the electrode.


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A carbon paste electrode modified with dithizone (diphenylthiocarbazone) was employed for quantification of lead from aqueous solutions. Lead(H) was chemically deposited on the chemically modified electrode (CME) by complexation with the modifier, and the electrode was transferred to an electrochemi