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Theories of catalysis

✍ Scribed by Weedy, S. K.

Publisher
Wiley (John Wiley & Sons)
Year
1926
Weight
417 KB
Volume
45
Category
Article
ISSN
0368-4075

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✦ Synopsis

problciii of cntnlysis is of iinmciisc iiiipoitnncc to tlic iiidustrinl clicmist, n~lio, Iion~cvcr, rarely 1ins tiiiic to Iiccp abmnst of thc nlrcady voluniinous mid ciw-i~icrcnsing litcrnturc on tlic subjcct. Tlic purpose of this article is to pitsciit n bricf-nccoiiiit of tlic cnrlicr resenrelics 011 tlic subjcct, togctlicr wit.Ii n iiiopc dctnilcd nccount, of thc rccciit nclvnnces. :I'XTROD IYC'l'lON "hc lirst rccorrlctl obscrvntion of ciitalytic chniqy was probnbly innclc 113' Kirclilioff in 1512 (Schzceigger's J., lSl2, 4, 10s). Rirchlioff foiiiid t h n t hot aqucous solutions of ~llincrnl acids convcrt stiirch into destrow and sucrosc without untlcrgohig niiy cliniigc. Ilcrzclius in 1836 (Jahrc.s6cricl~tc fur CILeniie, 1S3G) clnssifictf scvernl rcnctions of this type ~Jiicli, he coilsidcrcd, were duc to soinc Iicw force, " cntalytic force." Iiicludccl in Bcrzclius's list were : tdic dccomposition of Iiydrogcn pcrosidc by iiictnls (!~liciin.rcl, iJtt71..

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