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Theoretical study on thermal decomposition of azoisobutyronitrile in ground state

โœ Scribed by Chengke Sun; Hongmei Zhao; Zonghe Li

Publisher
SP Science China Press
Year
2004
Tongue
English
Weight
599 KB
Volume
47
Category
Article
ISSN
1674-7291

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Solvation effect in thermal decompositio
Solvation effect in thermal decomposition of 2,2โ€ฒ-azoisobutyronitrile on the N,N-dimethylformamide/acrylonitrile system
โœ J. Szafko; W. Feist; B. Pabin-Szafko ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 528 KB

The thermal decomposition rate constant of AIBN ( k d ) in N,N-dimethylformamide (DMF)/ acrylonitrile (AN) mixtures of various compositions at 60ยฐC is studied. The k d value is (6.45 +. 0.3) X min-' for pure acrylonitrile. The k d values of DMF/AN mixtures were found to be dependent on the mixture