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Theoretical study on the substitution reactions of fluorosilylenoid H2SiLiF with SiH3XHn−1(X

✍ Scribed by Qi, Yuhua; Xu, Chongjuan; Ma, Jing; Geng, Bing; He, Maoxia

Book ID
121580625
Publisher
Springer
Year
2014
Tongue
English
Weight
402 KB
Volume
25
Category
Article
ISSN
1040-0400

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✍ Chaojie Wang; Song Ye 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 229 KB 👁 1 views

The insertion reactions of the titanium atom cation Ti F into HF, HCl, H O, H S, NH , PH , CH , and SiH have been studied by ab initio molecular orbital 2 2 3 3 4 4 theory. All these reactions involve the initial formation of an intermediate complex followed by a hydrogen migration process via a tr