Theoretical study on the reactions of CH 3 NHNH 2 with ground state O( 3 P) atom and excited state O( 1 D) atom
โ Scribed by Wang, Li; Wang, Na; He, Hongqing; Zhang, Jinglai
- Book ID
- 125846822
- Publisher
- Taylor and Francis Group
- Year
- 2013
- Tongue
- English
- Weight
- 323 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0026-8976
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The reactions of 0( 'P) atoms with CH,OH and CH,CHOH have been measured directly for the first time. In a discharge flow reactor CH,OH/CH,CHOH profiles were monitored at ambient temperature and in an excess of 0 atoms by a mass spectrometer, working at low electron energies. The effect of subsequent
## Abstract The theoretical investigations were performed on the reaction mechanisms for the title reactions CH~3~C(O)CH~3~ + Cl โ products (R1), CH~3~C(O)CH~2~Cl + Cl โ products (R2), CH~3~C(O)CHCl~2~ + Cl โ products (R3), and CH~3~C(O)CCl~3~ + Cl โ products (R4) by __ab initio__ direct dynamics a