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Theoretical study on the reaction mechanism of excited-state 1,3 hydrogen transfer in formamide

✍ Scribed by Hidetsugu Tanaka; Kichisuke Nishimoto


Book ID
119117246
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
376 KB
Volume
181
Category
Article
ISSN
0166-1280

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The excited-state isomerization of 2-hydroxypyridine to 2( lH)-pyridone is considered as a model for UV photo-induced intramolecular hydrogen (or proton) transfer in systems without an intramolecular hydrogen bond. The potential energy functions of the electronic ground as well as of the lowest nn'