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Theoretical study on the hydrogen abstraction reactions of CF3CHFCF3 and CF3CF2CHF2 with X atoms (X=F, Cl, and Br)

✍ Scribed by Fan, Yanhua; Wen, Jinmiao; Zhao, Yuan; Wang, Li


Book ID
122005480
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
508 KB
Volume
150
Category
Article
ISSN
0022-1139

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A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.

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## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical