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Theoretical study on coordination of CO2 to third row metal atoms (CaMn, Cu, Zn)

✍ Scribed by Gwang-Hi Jeung


Book ID
103035231
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
590 KB
Volume
232
Category
Article
ISSN
0009-2614

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Theoretical study on coordination of CS2
✍ Gwang-Hi Jeung 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 417 KB

Bond strengths, stable geometries, and electron distributions in the lowest states of MCS 2 (M = Ca, Sc, Ti, V, Cr, Mn, Cu, Zn) are compared with the MCO 2 molecules by ab initio calculations. All the MCS 2 molecules except ZnCS 2 are shown to be stable with respect to dissociation into M + CS 2. On