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Theoretical study on chiral recognition mechanism of ethyl-3-hydroxybutyrate with permethylated β-cyclodextrin

✍ Scribed by Jie-hua Shi; Ying Hu; Zuo-jing Ding

Book ID
116379930
Publisher
Elsevier
Year
2011
Tongue
English
Weight
549 KB
Volume
973
Category
Article
ISSN
2210-271X

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✍ Arnaud Grandeury; Samuel Petit; Géraldine Gouhier; Valérie Agasse; Gérard Coquer 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 703 KB

It is shown that racemic 1-(p-bromophenyl)ethanol (p-Br-PE) can be quantitatively resolved by successive recrystallizations of (1:1) supramolecular complexes formed with permethylated b-cyclodextrin (TMb-CD). The two enantiomerically pure complexes were characterized by physical methods and their cr