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Theoretical study of Ziegler-Natta olefin polymerization mechanisms on heterogeneous catalysts and on homogeneous catalysts by using ``PIO'' analysis and ``LFO'' calculation

✍ Scribed by A. Shiga; M. Kubota


Book ID
110380974
Publisher
Springer US
Year
1997
Tongue
English
Weight
413 KB
Volume
48
Category
Article
ISSN
1011-372X

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Ethylene polymerization with homogeneous
✍ Roberto Fusco; Luca Longo; Francesco Masi; Fabio Garbassi πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 420 KB πŸ‘ 1 views

## Abstract The thermodynamics of the reaction of an ethylene molecule with the Cp~2~TiCH~3~Cl/Al(CH~3~)~2~Cl system (Cp = Ξ·~5~‐C~5~H~5~), as a model for olefin polymerization with homogeneous Ziegler‐Natta catalysts, was investigated via quantum mechanical DFT calculations. The comparison of the c